Photocatalytic properties of ZnO nanoparticle coating on porous ceramic substrates with varying porosities produced from fly ash and red mud


Özcan M., Birol B., Dülger Kutlu Ö., Kaya F.

International Journal of Applied Ceramic Technology, cilt.21, sa.3, ss.1995-2009, 2024 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 21 Sayı: 3
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1111/ijac.14635
  • Dergi Adı: International Journal of Applied Ceramic Technology
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, Chemical Abstracts Core, Communication Abstracts, Compendex, INSPEC, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1995-2009
  • Anahtar Kelimeler: fly ash, porous ceramics, red mud, sol–gel coating, ZnO nanoparticles
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

In order to improve filtering efficacy, nanoparticles are often deposited as photocatalytic degrading agents onto porous ceramics. This study aimed to deposit ZnO nanoparticles on ceramic substrates produced from fly ash and red mud with adjustable porosity and investigate their photocatalytic properties. To achieve this goal, at first porous ceramics were produced and sintered at various temperature/time intervals. It was observed that sintering at 800°C for 120 min provided a proper structure and porosity. In addition, MgO replacement with MgCO3 lowered the water absorption of the samples from 25.63% to 11.45%. The samples were then coated with ZnO nanoparticles using the sol–gel method and the ZnO structures obtained were micron-sized plates. It was observed that increasing porosity increased the ZnO amount and accordingly the photocatalytic properties of the products. During the adsorption tests conducted in the dark, the coated ceramic samples were stained with MB with a maximum MB adsorption ratio of ∼14%. On the other hand, no visible MB stain was observed on the samples that were exposed to UV irradiation, and the MB removal after the UV irradiation was 93.6%; therefore, it was concluded that the dominant MB removal mechanism was photocatalytic.