4-methyl-4-[2-(naphthalene)-2-oxoethyl] morpholin-4-ium iodide as a water soluble photoinitiator Jodek 4-metylo-4-[2-(naftalen-2-ylo)-2-oksoetylo]morfolin-4-iowy jako rozpuszczalny w wodzie fotoinicjator

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Ozcan F., Dogruyol Z., Doğruyol S.

Polimery/Polymers, cilt.68, sa.4, ss.215-220, 2023 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 68 Sayı: 4
  • Basım Tarihi: 2023
  • Doi Numarası: 10.14314/polimery.2023.4.3
  • Dergi Adı: Polimery/Polymers
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aerospace Database, Central & Eastern European Academic Source (CEEAS), Communication Abstracts, Compendex, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.215-220
  • Anahtar Kelimeler: photopolymerization, quaternary ammonium salt, water-soluble photoinitiators
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

Quaternary ammonium salt namely 4-methyl-4-[2-(naphthalen-2-yl)-2-oxoethyl] morpholin-4-ium iodide (WSMPM) was synthesized and characterized. High molar absorptivity at 347 nm (1910 L · mol-1 · cm-1) and good solubility in distilled water (10-2 M) allows WSMPM to be used as an effective photoinitiator also in water-soluble systems. Photopolymerization of acrylamide monomer with WSMPM (10-3 M) and a tertiary amine (N-methyldiethanolamine), resulted in 84.4% monomer to polymer conversion. Based on laser photolysis and electron spin resonance, a photoinitiator mechanism was proposed.