Synthesis of new polyhedral oligomeric silsesquioxane derivatives as some possible antimicrobial agents


Ersoy E. B., GÜNKARA Ö. T., OCAL N.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.194, sa.3, ss.257-268, 2019 (SCI-Expanded) identifier identifier

Özet

1,3-Dipolar cycloaddition reactions were studied to synthesize Polyhedral oligomeric silsesquioxane (POSS)-based norbornyl imide derivatives containing izoxazoline groups in good yields. And also 1,3-dipolar cycloaddition reactions of azomethine ylides with POSS-based norbornene dipolarophiles for a synthesis of the novel POSS-based norbornane-fused spiro-1,3-indandionolylpyrrolidines are reported. All newly synthesized POSS compounds were structurally characterized by FTIR, H-1, C-13 NMR, HRMS and GC/MS analyses.