Boron removal from geothermal brine using hybrid reverse Osmosis/Microbial desalination cell system


Goren A. Y., Jarma Y., KABAY N., Baba A., Okten H.

Separation and Purification Technology, vol.309, 2023 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: 309
  • Publication Date: 2023
  • Doi Number: 10.1016/j.seppur.2022.123006
  • Journal Name: Separation and Purification Technology
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Biotechnology Research Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, INSPEC, Metadex, Pollution Abstracts, Civil Engineering Abstracts
  • Keywords: Energy production, Geothermal Brine, Irrigation Water, Microbial Desalination Cell, Reverse Osmosis
  • Yıldız Technical University Affiliated: No

Abstract

Agriculture sector leads worldwide as the most water consuming sector with water demand. Since natural water resources cannot keep up with the demand, a shift from conventional water resources to unconventional ones is needed. While geothermal water was gaining importance for its energy content, small-scale (<10 L/s) energy plants were not required to reinject their spent geothermal brine. As geothermal resources align with agricultural areas in Western Anatolia, discharge of untreated brine might have severe adverse effects on crop yields and soil quality. In this study, we investigated use of spent geothermal brine for irrigation after treatment with Reverse Osmosis/Microbial Desalination Cell (RO/MDC) hybrid process. Treatment efficiencies for B, COD, As, Li, Fe, Cr concentrations and energy production values were determined. Treated water was initially evaluated for irrigation considering three quality categories (I, II, and III) comprised of parameters such as electrical conductivity (EC), total dissolved solids (TDS), and sodium adsorption ratio (SAR), along with sodium, chloride and boron concentrations. Additionally, magnesium adsorption ratio (MAR) and permeability index (PI) were used to evaluate for irrigation suitability. Although B concentrations in MDC-treated permeate (3.29 mg/L) and concentrate (2.99 mg/L) streams were not low enough to meet Quality I criterion (<0.7 mg/L), they can be still utilized in irrigation of moderate-to-high tolerant plants. Furthermore, PI and MAR parameters pointed to suitability for irrigational use.