Synthesis and Characterization of Novel Peripherally 3-Bromo-1-Phenyl-1-Propene Derivative of Porphyrazine

KESKİN B., Avciata U., Guel A.

9th Eurasia Conference on Chemical Sciences, Antalya, Turkey, 9 - 13 September 2006, pp.389-390 identifier

  • Publication Type: Conference Paper / Full Text
  • Doi Number: 10.1007/978-1-4020-6955-0_46
  • City: Antalya
  • Country: Turkey
  • Page Numbers: pp.389-390
  • Yıldız Technical University Affiliated: Yes


Magnesium porphyrazines substituted with eight (phenyl-propene) groups on the peripheral positions have been prepared by cyclotetramerization of 1,2-bis(3-phenyl-2-propenethio) maleonitrile and then achieved porphyrazine by 3-bromo-1-phenyl-1-propene. Metal-free derivative was obtained by its treatment with trifluoroacetic acid. The new compounds have been characterized by FT-IR, H-1-NMR, UV-VIS and elemental analysis methods.