Synthesis and characterisation of D-pi-D type Schiff base ligands derived from fluorene and 1,10-phenanthroline and its complexes with ruthenium(II)

ELMALI F., ERDEN İ., DEMİRHAN N., Avciata U.

JOURNAL OF CHEMICAL RESEARCH, no.2, pp.90-92, 2009 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Publication Date: 2009
  • Doi Number: 10.3184/030823409x402537
  • Journal Name: JOURNAL OF CHEMICAL RESEARCH
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.90-92
  • Keywords: Schiff base, D-pi-D, complex, fluorene, 1,10-phenanthroline, TRANSITION-METAL-COMPLEXES, DNA-BINDING, POLYPYRIDYL COMPLEXES, CHEMISTRY, ION
  • Yıldız Technical University Affiliated: Yes

Abstract

A fluorene derivative, 9H-fluoren-9-one(diphenylmethylene)hydrazone has been synthesised from the reaction of 4,5-diazafluoren-9-one with benzophenone hydrazone and a 1,10-phenanthroline derivative, N-[(1E,2E)-3-phenylprop-2en-1-ylidene]-1,10-phenanthrolin-5-amine has been synthesised from the reaction of 5-amino-1,10-phenanthroline with cinnamaldehyde. Ru(II) complexes of these ligands have been prepared and characterised.