Synthesis and characterization of new thiourea derivatives substituted 1,10-phenanthroline and crown ether

Elmali F., Avciata U., DEMİRHAN N.

MAIN GROUP CHEMISTRY, cilt.10, sa.1, ss.17-23, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 10 Sayı: 1
  • Basım Tarihi: 2011
  • Doi Numarası: 10.3233/mgc-2010-0020
  • Dergi Adı: MAIN GROUP CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.17-23
  • Anahtar Kelimeler: Thiourea, 1,10-phenanthroline, crown ether, isothiocyanate, METAL-IONS, COMPLEXES, SODIUM, POLYETHERS, NICKEL(II), LIGAND
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

New organic compounds that could serve as ligands for metals or in supramolecular assemblies were prepared by combining various amines and isothionates. This resulted in the new thiourea derivatives: 5,6-bis[aminoanilinomethanethione][1,10] phenanthroline (1), 1,2-bis[aminobenzo(15-crown-5)]-15-ylaminomethanethionebenzene (2), 5,6-bis[aminobenzo(15-crown-5)]-15-ylaminornethanethione[1,10]phenanthroline (3), and N-[1, 10-phenanthroline]-N'-[[benzo-15-crown-5] yl]thiourea (4). The structures and compositions of the compounds have been confirmed by elemental analyses, UV-vis, FTIR, H-1 NMR (DMSO-d(6)), C-13 NMR (DMSO-d(6)) and MS spectra.