New 2-D silver(I) coordination network constructed from thiomethyl group-substituted p-tert-butylthiacalix[4]arene

Akdaş Kılıç H., Graf E., Hosseini M. W., Kyritsakas N.

TURKISH JOURNAL OF CHEMISTRY, vol.46, no.5, pp.1541-1547, 2022 (SCI-Expanded) identifier identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 46 Issue: 5
  • Publication Date: 2022
  • Doi Number: 10.55730/1300-0527.3459
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.1541-1547
  • Keywords: Molecular networks, coordination polymer, thiacalix[4]arene, X-ray structure, thioether
  • Yıldız Technical University Affiliated: Yes


New ligand based on p-tertbutyltetrathiacalix[4]arene blocked in 1,3-alternate conformation, was achieved via a multistep synthesis with the introduction of thiomethylpropoxy groups on the lower rim which leads to a neutral tecton. The combination of this p-tertbutyltetrathiacalix[4]arene (p-TCA-2), in 1, 3-alternate imposed conformation, with tetrahedral Ag(I)SbF6 salt, leads to the formation of neutral, new 2-D coordination network, which was structurally investigated in the solid state by X-ray diffraction methods on a single crystal.