Modulation of emission properties of phosphine-sulfonate ligand containing copper complexes: playing with solvato-, thermo-, and mechanochromism

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Vacher A., Amar A., Camerel F., Molard Y., Latouche C., Roisnel T., ...Daha Fazla

DALTON TRANSACTIONS, cilt.48, sa.6, ss.2128-2134, 2019 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 48 Sayı: 6
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1039/c8dt04502j
  • Dergi Adı: DALTON TRANSACTIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2128-2134
  • Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

Modulations of various neutral phosphine containing copper(I) complexes exhibiting phosphorescence and TADF are easily achieved by solvent modification restricting intramolecular rotation or by modifying the L-X phosphine-sulfonate chelate. This concept is not limited to solvents as the addition of metallic salts also led to the formation of original well-defined photoluminescent K2CuLX3 and KCuL2X2 cuprate complexes.