Modulation of emission properties of phosphine-sulfonate ligand containing copper complexes: playing with solvato-, thermo-, and mechanochromism

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Vacher A., Amar A., Camerel F., Molard Y., Latouche C., Roisnel T., ...More

DALTON TRANSACTIONS, vol.48, no.6, pp.2128-2134, 2019 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 48 Issue: 6
  • Publication Date: 2019
  • Doi Number: 10.1039/c8dt04502j
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.2128-2134
  • Yıldız Technical University Affiliated: No


Modulations of various neutral phosphine containing copper(I) complexes exhibiting phosphorescence and TADF are easily achieved by solvent modification restricting intramolecular rotation or by modifying the L-X phosphine-sulfonate chelate. This concept is not limited to solvents as the addition of metallic salts also led to the formation of original well-defined photoluminescent K2CuLX3 and KCuL2X2 cuprate complexes.