Photoinitiated polymerization of ethyl cyanoacrylate by phosphonium salts
ANGEWANDTE MAKROMOLEKULARE CHEMIE, cilt.264, ss.56-59, 1999 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 264
- Basım Tarihi: 1999
- Dergi Adı: ANGEWANDTE MAKROMOLEKULARE CHEMIE
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.56-59
- Yıldız Teknik Üniversitesi Adresli: Evet
Özet
The photoinitiated polymerization of ethyl cyanoacrylate (ECA) by benzyl triphenylphosphonium hexafluoroantimonate (BP+) and (anthracen-9-ylmethyl)triphenylphosphonium hexafluoroantimonate (MAP(+)) was studied. Zwitterionic and free radical mechanisms which involved homolytic and heterolytic decomposition of the phosphonium salts are discussed. The anthracene-sensitized photopolymerization of ECA was also demonstrated.