Electronic energy levels of CsCdCl3

Demirbilek R., Çelik Bozdoğan A. , Çalışkan M., Asan G., Özen G.

Journal Of Luminescence, vol.131, pp.1853-1856, 2011 (Journal Indexed in SCI)

  • Publication Type: Article / Article
  • Volume: 131
  • Publication Date: 2011
  • Title of Journal : Journal Of Luminescence
  • Page Numbers: pp.1853-1856


The excitation and emission spectra of CsCdCl3 crystal grown by the Bridgman growth technique, are

observed. Its dominant excitation spectra correspond to the transitions between the electronic energy

levels of the face-shared [CdCl6]4 octahedron complexes with C3v symmetry. With the help of the

molecular orbital diagram of the [CdCl6]4 molecule complex, an approximate electronic energy level

diagram of this crystal is constructed using one-electron approximation.