Synthesis and Characterization of Novel Peripherally 3-Bromo-1-Phenyl-1-Propene Derivative of Porphyrazine


KESKİN B. , Avciata U. , Guel A.

9th Eurasia Conference on Chemical Sciences, Antalya, Türkiye, 9 - 13 Eylül 2006, ss.389-390 identifier

  • Yayın Türü: Bildiri / Tam Metin Bildiri
  • Doi Numarası: 10.1007/978-1-4020-6955-0_46
  • Basıldığı Şehir: Antalya
  • Basıldığı Ülke: Türkiye
  • Sayfa Sayıları: ss.389-390

Özet

Magnesium porphyrazines substituted with eight (phenyl-propene) groups on the peripheral positions have been prepared by cyclotetramerization of 1,2-bis(3-phenyl-2-propenethio) maleonitrile and then achieved porphyrazine by 3-bromo-1-phenyl-1-propene. Metal-free derivative was obtained by its treatment with trifluoroacetic acid. The new compounds have been characterized by FT-IR, H-1-NMR, UV-VIS and elemental analysis methods.