Advanced tetra amino (ATA-100) cobalt(II) phthalocyanine-based metallo-covalent organic polymer for sensitively detecting volatile organic compounds

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Güney G., Kaplan G. a., Taşaltin C., Gürol İ.

Turkish Journal of Chemistry, cilt.47, sa.5, ss.1138-1148, 2023 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 47 Sayı: 5
  • Basım Tarihi: 2023
  • Doi Numarası: 10.55730/1300-0527.3600
  • Dergi Adı: Turkish Journal of Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.1138-1148
  • Anahtar Kelimeler: covalent organic polymer (COP), Phthalocyanine (Pc), sensor, surface acoustic wave (SAW), volatile organic compounds (VOCs)
  • Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

The synthesis and characterization of a novel covalent organic polymer cobalt (II) phthalocyanine (ATA-100) including tetra amino group is described for the first time. This covalent organic polymer (COP) is characterized by FTIR, TGA, RAMAN, PXRD, and SEM-EDS. The developed sensor is tested for acetone, ethyl butyrate, n-hexane, chloroform, and n-butyraldehyde in a range of 80–10,900 ppm. ATA-100 showed the highest sensitivity for ethyl butyrate. The results have confirmed the possibility of utilizing ATA-100 COP-based surface acoustic wave (SAW) sensors for a wide variety of applications, including indoor air quality and environmental monitoring of volatile organic compounds (VOCs).