High-Power Rapid Laser-Induced Synthesis of Multi-functional Cobalt Metal-Organic Framework With an Unprecedented Synthesis Efficiency


MUTLU S., Ortaç B., Karatutlu A., Gorkan T., Durgun E., Soyler D., ...Daha Fazla

Advanced Materials Technologies, 2026 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1002/admt.202502487
  • Dergi Adı: Advanced Materials Technologies
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Compendex, INSPEC
  • Anahtar Kelimeler: density functional theory (DFT), electrochemical sensing, laser technique, metal-organic framework, Rietveld analysis
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

A rapid, high-yield laser-assisted synthesis route with an exceptional production efficiency (≥90%) is introduced for cobalt-based metal–organic frameworks (Co-MOFs), producing ordered hybrid structures within an hour that integrate optical, magnetic, and adsorption functionalities. The Co-MOFs exhibit tunable properties, including a low-temperature paramagnetic transition confirmed by magnetic measurements and first-principles calculations. Gas adsorption studies reveal promising performance for N2, CH4, and CO2, combining low energy consumption with cost-effective gas separation. Structural analysis indicates mesoporosity with high accessibility, supporting selective uptake under practical conditions. Importantly, Co-MOF-modified graphite electrodes demonstrate outstanding electrochemical sensing performance for dopamine, achieving a low detection limit (5.5 µM), high sensitivity (121 µA mM−1 cm−2), and excellent reproducibility in human serum. These results underline the multifunctional potential of laser-synthesized Co-MOFs as scalable platforms that couple sustainable gas separation with biomedical diagnostics, advancing the development of framework materials for real-world applications.