Temperature effect on the recovery process in stretched Bombyx mori silk fibers


AKSAKAL B.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.152, ss.629-636, 2016 (SCI İndekslerine Giren Dergi)

  • Cilt numarası: 152
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1016/j.saa.2015.01.105
  • Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Sayfa Sayısı: ss.629-636

Özet

The recovery process in stretched Bombyx mori silk fibers at different strain levels from 3% to 17% was investigated at room conditions during long period of time from 5 min to 20 days and more. How the temperature affects the recovery process in the silk fibers stretched at room conditions was examined at temperatures from 25 to 125 degrees C. The results of the recovery process at 25 degrees C revealed that although the recovery process from strain values higher than 3% strain continued slowly which caused quite high remaining deformation, a complete recovery from 3% strain was observed after 3 days. However, better recovery process was observed with increasing temperature which led to lower remaining deformations. For instance, a complete recovery from 6% strain was observed after 144 h and 3 h for the recovery process at 100 degrees C and 125 degrees C, respectively which indicates an important result that the deformations induced by stretching the silk fibers up to 6% strain are reversible and increasing temperature affects the velocity of this process significantly. The recovery process expressed in the strain (epsilon) and logarithm time coordinates showed a linear dependence for which a linear equation was proposed. Thus, this linear equation enables to estimate the required time for a complete recovery from different strain levels and remaining deformation at any stage of the recovery at different temperatures. The ATR-FTIR spectra of the stretched silk fibers during the recovery process revealed some changes in the absorbance ratios and shifts in the positions of the bands assigned to C-alpha-C, N-H stretching vibrations, and the Amide III mode. It was suggested that new formation of the hydrogen bonds between polypeptide chains especially in amorphous regions and the changes in the intra-sheet hydrogen bonds in beta-sheet crystalline regions greatly contribute to the recovery process. (C) 2015 Elsevier B.V. All rights reserved.