Akademik Veri Yönetim Sistemi
Physica B: Condensed Matter, cilt.690, 2024 (SCI-Expanded)
Spinel compounds, classified as ceramics, have exhibited excellent industrial application features. The spinel form of cobalt aluminate was successfully synthesized by using the co-precipitation method. A comprehensive explanation of spinel cobalt synthesis was provided, including thermodynamics and non-isothermal kinetic modelling of the transformation process of cobalt-aluminium complexes into CoAl2O4. The synthesized blue-coloured powder was identified as Spinel (CoAl2O4) with the cubic crystal system. In the morphological analyses, particle sizes were varied in the range of 130–250 nm. The CoAl2O4 formation was explained by a three-step reaction and the Coast-Redfern non-isothermal kinetic method. The averages of activation energies were found as 53.42 kJ/mol, 56.19 kJ/mol and 380.25 kJ/mol for the first, second and third steps of the thermal process, respectively. The synthesis reaction was found to be endothermic and non-spontaneous based on calculations of thermodynamic functions of ΔH, ΔG, and ΔS by using activated complex theory.