Modification of polyhedral oligomeric silsesquioxane derivatives with heck reaction as possible new bio-hybrid materials


GÜNKARA Ö. T.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol.194, no.9, pp.909-916, 2019 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 194 Issue: 9
  • Publication Date: 2019
  • Doi Number: 10.1080/10426507.2019.1576678
  • Title of Journal : PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Page Numbers: pp.909-916

Abstract

The regioselective synthesis of Polyhedral oligomeric silsesquioxane (POSS)-based norbornyl imide derivatives through palladium catalyzed Heck coupling reaction was reported on an effective synthetic method to organic-inorganic bio-hybrids serving as advanced materials. The reaction of POSS-based imide derivatives with various aryl iodides catalyzed by palladium acetate in the presence of triethyl amine, as the base, in DMF afforded the products in moderate yields. All new POSS derivatives were structurally characterized by FTIR, H-1, C-13 NMR, HRMS and GC/MS analyses.