The effect of the amine structure on photoinitiated free radical polymerization of methyl methacrylate using bisketocoumarin dye
PROGRESS IN ORGANIC COATINGS, cilt.59, sa.4, ss.274-277, 2007 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Derleme
- Cilt numarası: 59 Sayı: 4
- Basım Tarihi: 2007
- Doi Numarası: 10.1016/j.porgcoat.2007.03.005
- Dergi Adı: PROGRESS IN ORGANIC COATINGS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.274-277
- Anahtar Kelimeler: photoinitiator, bisketocoumarin, amine, polymerization, RT-FTIR, SYSTEMS, DERIVATIVES
- Yıldız Teknik Üniversitesi Adresli: Evet
Özet
Photoinitiation of the polymerization of methyl methacrylate by the bis-diethylaminocoumarin dye (BKC) in the presence of various amines was studied in order to determine the efficient amine that leads to the formation of the initiating radicals. RT-FTIR studies were also performed for multifunctional methacrylate. According to photoinduced polymerization and RT-FIR studies, N-methyldiethanol amine was the more efficient H-donor compared with the others. (c) 2007 Elsevier B.V. All rights reserved.