The synthesis and characterization of aryloxy-linear phosphazenes
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.178, sa.5, ss.1037-1046, 2003 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 178 Sayı: 5
- Basım Tarihi: 2003
- Doi Numarası: 10.1080/10426500390208875
- Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1037-1046
- Yıldız Teknik Üniversitesi Adresli: Hayır
Özet
The reactions of N-dichlorophosphoryl-P-trichloromonophosphazene with sodium o-methylphenoxide, sodium p-methylphenoxide, sodium alpha-naphthalenoxide, monosodium 4-(2-pyridylazo)resorcinol, and sodium 1-nitroso-2-naphthaleneoxide have been investigated. Experimental studies were carried out in argon atmosphere. The sodium aryloxides were prepared from naphthalene or phenol derivatives and metallic sodium. The phosphazene and phenolate or naphthaleneoxide were reacted at 0degreesC and then refluxed. After the reaction products were separated by using column chromatography, the structures of the compounds were defined by elemental analysis, IR, H-1, C-13, (PNMR)-P-31, and mass spectroscopy.