Synthesis, spectral and photophysical investigation of porphyrazines with eight 3-quinolinecarboxy esters

Kilicarslan F., ERDOĞMUŞ A., Coskun N. Y., Yalcin S. M., Gül A.

JOURNAL OF COORDINATION CHEMISTRY, cilt.66, sa.24, ss.4316-4329, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 66 Sayı: 24
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1080/00958972.2013.867035
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.4316-4329
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

In this study, the syntheses and characterization of [2,3,7,8,12,13,17,18-octakis [2-(3-quinolincarboxy)ethylhio] porphyrazinato (NNNN24)-N-21-N-22-N-23] magnesium(II), quaternized [2,3,7,8,12,13,17,18-octakis [2-(3-quinolincarboxy)ethylhio] porpyrazinato (NNNN24)-N-21-N-22-N-23] magnesium(II), [2,3,7,8,12,13,17,18-octakis[2-(3-quinolinecarboxy)-ethylthio]21H23H (NNNN24)-N-21-N-22-N-23 porphyrazine and [2,3,7,8,12,13,17,18-octakis[2-(3-quinolinecarboxy)-ethylthio]porphyrazinato (NNNN24)-N-21-N-22-N-23} zinc are described. The new compounds have been characterized by elemental analysis, FT-IR, H-1-NMR, and mass spectra. General trends are described for fluorescence quantum yields of these compounds in dimethylsulfoxide (DMSO). In this study, the effects quaternization of the substituents on the photophysical and spectroscopic properties are also reported.