2-methylol-thioxanthone as a free radical polymerization initiator

TEMEL, Gokhan; Arsu, Nergis

doi:10.1016/j.jphotochem.2007.04.016

2-methylol-thioxanthone as a free radical polymerization initiator

Atıf İçin Kopyala

TEMEL G., Arsu N.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, cilt.191, ss.149-152, 2007 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 191
Basım Tarihi: 2007
Doi Numarası: 10.1016/j.jphotochem.2007.04.016
Dergi Adı: JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.149-152
Yıldız Teknik Üniversitesi Adresli: Evet

Özet

2-Methylol-thioxanthone (TX-M) was synthesized and characterized as a new photoinitiator. Photopolymerization experiments were performed with methyl methacrylate and also trimethylolpropanetriacrylate (TMPTA) as a multifunctional monomer in the presence of TX-M with N-methyl diethanol amine. Polymerization did not occur in an air atmosphere with TX-M without adding MDEA. The inhibiting effect of oxygen on the rate of polymerization was observed to be due to quenching of the triplet radicals by the carbonyl compound (TX-M). (c) 2007 Elsevier B.V. All rights reserved.