Lead Acetate Based Hybrid Perovskite Through Hot Casting for Planar Heterojunction Solar Cells


Shin G. S. , Choi W., Na S., Gokdemir F. P. , Moon T.

ELECTRONIC MATERIALS LETTERS, cilt.14, ss.155-160, 2018 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 14 Konu: 2
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1007/s13391-018-0042-1
  • Dergi Adı: ELECTRONIC MATERIALS LETTERS
  • Sayfa Sayısı: ss.155-160

Özet

Flawless coverage of a perovskite layer is essential in order to achieve realistic high-performance planar heterojunction solar cells. We present that high-quality perovskite layers can be efficiently formed by a novel hot casting route combined with MAI (CH3NH3I) and non-halide lead acetate (PbAc2) precursors under ambient atmosphere. Casting temperature is controlled to produce various perovskite microstructures and the resulted crystalline layers are found to be comprised of closely packed islands with a smooth surface structure. Lead acetate employed perovskite solar cells are fabricated using PEDOT:PSS and PCBM charge transporting layers, in p-i-n type planar architecture. Especially, the outstanding open-circuit voltage demonstrates the high crystallinity and dense coverage of the produced perovskite layers by this facile route.