The synthesis and characterization of cycloalkoxy-linear phosphazenes


Ozturk A., Aslan F., Cil E., Arslan M. , Kilic A.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol.178, no.10, pp.2097-2105, 2003 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 178 Issue: 10
  • Publication Date: 2003
  • Doi Number: 10.1080/10426500390221537
  • Title of Journal : PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Page Numbers: pp.2097-2105

Abstract

The reactions of N-dichlorophosphoryl-P-trichlorophosphazene, Cl3P=N-P(O)Cl-2 with the sodium salts of cyclopentanol, cyclohexanol, 4-methylcyclohexanol, 3-methylcyclohexanol, 3-methylcyclopentanol are discussed. Pentacycloalkoxy-substituted phosphazenes were obtained from cyclopentanol, 4-methylcyclohexanol, 3-methylcyclohexanol, 3-methylcyclopentanol. Tetrasubstituted derivative also was obtained from cyclohexanol at the same conditions. The structure of products was defined by IR, H-1, C-13, P-31 NMR, and mass spectroscopy.