The synthesis and characterization of cycloalkoxy-linear phosphazenes

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Ozturk A., Aslan F., Cil E., Arslan M., Kilic A.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.178, sa.10, ss.2097-2105, 2003 (SCI-Expanded, Scopus)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 178 Sayı: 10
• Basım Tarihi: 2003
• Doi Numarası: 10.1080/10426500390221537
• Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.2097-2105
• Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

The reactions of N-dichlorophosphoryl-P-trichlorophosphazene, Cl3P=N-P(O)Cl-2 with the sodium salts of cyclopentanol, cyclohexanol, 4-methylcyclohexanol, 3-methylcyclohexanol, 3-methylcyclopentanol are discussed. Pentacycloalkoxy-substituted phosphazenes were obtained from cyclopentanol, 4-methylcyclohexanol, 3-methylcyclohexanol, 3-methylcyclopentanol. Tetrasubstituted derivative also was obtained from cyclohexanol at the same conditions. The structure of products was defined by IR, H-1, C-13, P-31 NMR, and mass spectroscopy.