Investigation of the Surface Properties of Hexagonal Boron Nitride and Boron Phosphate by Inverse Gas Chromatography at Infinite Dilution
JOURNAL OF CHROMATOGRAPHIC SCIENCE, cilt.61, ss.7-14, 2022 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 61
- Basım Tarihi: 2022
- Doi Numarası: 10.1093/chromsci/bmac017
- Dergi Adı: JOURNAL OF CHROMATOGRAPHIC SCIENCE
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Analytical Abstracts, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, CAB Abstracts, Chemical Abstracts Core, Chimica, EMBASE, Food Science & Technology Abstracts, MEDLINE, Pollution Abstracts, Veterinary Science Database
- Sayfa Sayıları: ss.7-14
- Yıldız Teknik Üniversitesi Adresli: Evet
Özet
The boron-based ceramics namely hexagonal boron nitride (h-BN) and boron phosphate (BPO4) were synthesized and characterized by Fourier transform infrared spectroscopy and X-ray diffraction analysis. The surface properties of h-BN and BPO4 were examined by inverse gas chromatography method. The dispersive surface energy and the acidic-basic character of h-BN, and BPO4 surfaces were estimated by the retention time with probes such as n-hexane, n-heptane, n-octane, n-nonane, n-decane, acetone, ethyl acetate, dichloromethane, chloroform and tetrahydrofuran at infinite dilution region. The dispersive surface free energies calculated using both Schultz and Dorris-Gray methods, decreased linearly with increasing temperature. The specific adsorption free energy and the specific adsorption enthalpy corresponding to acid-base surface interactions were determined. By correlating with the donor and acceptor numbers of the probes, the acidic and the basic parameters of the h-BN and BPO4 were calculated. The values obtained for and parameters indicated that h-BN has a basic character, whereas BPO4 has an acidic character.