Advancing circular economy in the pulp and paper sector with novel routes for microbial sulfur recovery


Unay E., TUNAY D., Ozkaya B.

International Journal of Hydrogen Energy, cilt.148, 2025 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 148
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1016/j.ijhydene.2025.05.435
  • Dergi Adı: International Journal of Hydrogen Energy
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Artic & Antarctic Regions, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, Environment Index, INSPEC
  • Anahtar Kelimeler: Bio-batteries, Circular economy, Kraft process, Li–S, MCDM, Sulfur cathode, Sulfur recovery
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

This study presents a novel microbial method for the pulp and paper industry to adopt circular economy practices by converting green liquor, a problematic waste stream, into a valuable energy storage material. Using haloalkaliphilic microorganisms, elemental sulfur is recovered under extreme pH and salinity conditions, achieving concentrations up to 2 g L−1 without chemical pretreatment. The recovered biogenic sulfur was purified and used as a high-value cathode material in lithium-sulfur (Li–S) batteries. Electrochemical tests show an initial specific capacity of approximately 550 mAh g−1, with redox peaks at ∼2.3 V, 2.0 V, and 2.5 V, confirming typical Li–S behavior. A multi-criteria decision-making analysis using the TOPSIS (Technique for Order of Preference by Similarity to Ideal Solution) method with AHP-derived weights ranks Li–S batteries highest among other battery chemistries, with a closeness coefficient (Pi) of 0.7352, outperforming alternatives in weight, cost, and energy output. Further research may improve sulfur purity, and electrode performance.