Synthesis of Cu(II)-Organophosphonate Framework with Predefined Void Spaces

Bulut A., Zorlu Y., KİRPİ E., Cetinkaya A., Worle M., Beckmann J., ...More

CRYSTAL GROWTH & DESIGN, vol.15, no.12, pp.5665-5669, 2015 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 15 Issue: 12
  • Publication Date: 2015
  • Doi Number: 10.1021/acs.cgd.5b01319
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.5665-5669
  • Yıldız Technical University Affiliated: Yes


Here we report the first utilization of the novel methane tetra-p-phenylphosphonic acid (MTPPA) ligand for the preparation of metal complexes with Cu(II). The hydrothermal and solvothermal reactions of tetratopic MTPPA as a bridging ligand in conjunction with the square pyramidal {Cu(terpy)}(2+) and {Cu-2(pbterpy)}(4+), (where terpy = 2,2':6',2 ''-Terpyridine and pbterpy = 4',4 ''''-(1,4-Phenylene)-bis(2,2':6',2 ''-terpyridine)) as prefixed corner building units have produced one-dimensional [{Cu(terpy)}(2)(MTPPA-H-5) (MTPPA-H-6)]center dot(4.2H(2)O)(H3O) (1) and two-dimensional [{Cu-2(pbterpy)}MTPPA-H-4] (2), respectively. The structures were characterized by single crystal X-ray diffraction and TGA.