Synthesis and Characterization of new D-pi-D Type Schiff Base Ligands by 1,10-Phenanthroline Derivatives and its Complexes with Ruthenium(II)

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Erden I.

ASIAN JOURNAL OF CHEMISTRY, vol.22, no.4, pp.2959-2964, 2010 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 22 Issue: 4
• Publication Date: 2010
• Journal Name: ASIAN JOURNAL OF CHEMISTRY
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.2959-2964
• Yıldız Technical University Affiliated: Yes

Abstract

The Schiff base ligands L(1) and L(2) with D-pi-D type have been synthesized from the reaction of 5-amino-1,10-phenanthroline and 5,6-diamino-1, 10-phenanthroline with 2-(hexyloxy)benzaldehyde. The ruthenium(II) complexes of these ligands were prepared and characterized. The ligands L(1), L(2) and ruthenium complexes have been characterized by FTIR, UV-visible, (1)H NMR and fluorescence spectra, as well as, elemental analyses and mass spectra.