Determination of trace nickel in spinach samples using the combination of vortex-assisted deep eutectic solvent-based liquid phase microextraction and slotted quartz tube-flame atomic absorption spectrometry

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Alacakoç B., Tekin Z., UNUTKAN T., ÇETİN G., BAKIRDERE S.

Atomic Spectroscopy, cilt.40, sa.6, ss.233-237, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 40 Sayı: 6
  • Basım Tarihi: 2019
  • Doi Numarası: 10.46770/as.2019.06.006
  • Dergi Adı: Atomic Spectroscopy
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.233-237
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

A novel, green, and efficient analytical method was developed for the preconcentration of nickel in spinach samples, prior to the determination by slotted quartz tube (SQT) - flame atomic absorption spectrometry (FAAS). Diphenylcarbazone was employed as the ligand, and a deep eutectic solvent (DES)-based liquid phase microextraction (LPME) was used to enrich the analyte for its determination at trace levels. All parameters of the SQT-FAAS and DES method were systematically optimized to enhance the detection power of conventional FAAS.