Preparation of poly(glycidyl methacrylate) grafted sulfonamide based polystyrene resin with tertiary amine for the removal of dye from water


Senkal B. F. , Bildik F., Yavuz E., Sarac A.

REACTIVE & FUNCTIONAL POLYMERS, vol.67, no.12, pp.1471-1477, 2007 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 67 Issue: 12
  • Publication Date: 2007
  • Doi Number: 10.1016/j.reactfunctpolym.2007.07.042
  • Title of Journal : REACTIVE & FUNCTIONAL POLYMERS
  • Page Numbers: pp.1471-1477

Abstract

Poly(glycidyl methacrylate) was grafted onto crosslinked poly (styrene) beads through the 2-chloroethyl sulphonamide (CSA) groups present in the resin using ATRP polymerization method. A beaded polymer with a poly (glycidyl methacrylate) surface shell was prepared in three steps, starting from poly (styrene-DVB) (10% crosslinking) based beads with a particle size of 420-590 mu m, according to the synthetic protocol; chlorosulfonation, sulfamidation with 2-chloroethylamine hydrochloride and grafting reaction of poly (glycidyl methacrylate).