Arylation reaction of N-dichlorophosphoryl-P-trichlorophosphazene

ARSLAN M., ASLAN F., ÖZTÜRK A. İ.

HETEROATOM CHEMISTRY, vol.14, no.2, pp.138-143, 2003 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 14 Issue: 2
  • Publication Date: 2003
  • Doi Number: 10.1002/hc.10114
  • Journal Name: HETEROATOM CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.138-143
  • Yıldız Technical University Affiliated: No

Abstract

The reactions of N-dichlorophosphoryl-P-trichlorophosphazene (Cl3P=N-POCl2) with phenylmagnesium chloride, o-tolylmagnesium chloride, p-tolylmagnesium chloride, p-chlorophenylmagnesium chloride, 2-mesitylmagnesium bromide, and 2-thienyl lithium were studied. The resulting pentaaryl phosphazenes R3P=N-P(O)R-2 were separated by using column chromatography, their structures were defined by IR, elemental analysis, H-1, C-13, P-31 NMR, and mass spectroscopy. (C) 2003 Wiley Periodicals, Inc.