A simple flow injection spectrophotometric determination method for iron(III) based on O-acetylsalicylhydroxamic acid complexation

Andac M., Asan A., IŞILDAK İ.

CHEMICAL PAPERS, cilt.63, sa.3, ss.268-273, 2009 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 63 Sayı: 3
  • Basım Tarihi: 2009
  • Doi Numarası: 10.2478/s11696-009-0024-8
  • Dergi Adı: CHEMICAL PAPERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.268-273
  • Anahtar Kelimeler: flow-injection analysis, iron(III), O-acetylsalicylhydroxamic acid, TOTAL IRON, WATER SAMPLES, CHEMILUMINESCENCE, SPECIATION, FE(III), PRECONCENTRATION, COPPER(II), FERROZINE, SYSTEM, ASSAY
  • Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

A simple and rapid flow-injection spectrophotometric method for the determination of iron(III) and total iron is proposed. The method is based on the reaction between iron(III) and O-acetylsalicylhydroxamic acid (AcSHA) in a 2 % methanol solution resulting in an intense violet complex with strong absorption at 475 nm. Optimum conditions for the determination of iron(III) and the interfering ions were tested. The relative standard deviation for the determination of 5 mu g L-1 iron(III) was 0.85 % (n = 10), and the limit of detection (blank signal plus three times the standard deviation of the blank) was 0.5 mu g L-1, both based on the injection volumes of 20 mu L. The method was successfully applied in the determination of iron(III) and total iron in water and ore samples. The method was verified by analysing a certified reference material Zn/Al/Cu 43XZ3F and also by the AAS method.