Modeling of absorption kinetics of poly(acrylamide) hydrogels crosslinked by EGDMA and PEGDMAs

İSMAİL O., KIPÇAK A. S., Piskin S.

RESEARCH ON CHEMICAL INTERMEDIATES, vol.39, no.3, pp.907-919, 2013 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Review
  • Volume: 39 Issue: 3
  • Publication Date: 2013
  • Doi Number: 10.1007/s11164-012-0604-z
  • Journal Name: RESEARCH ON CHEMICAL INTERMEDIATES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.907-919
  • Keywords: Hydrogel, PEGDMA, Crosslinked, Swelling, Diffusion, SWELLING CHARACTERIZATION, SEMI-IPNS, ACRYLAMIDE, TRANSPORT, RELEASE
  • Yıldız Technical University Affiliated: Yes

Abstract

In this study, acrylamide-based hydrogels are synthesized by free radical solution polymerization in aqueous solution using ethylene glycol dimethacrylate (EGDMA) and its derivative polyethylene glycol dimethacrylate (PEGDMA) with different molecular weights as crosslinkers in the solution medium. The Fourier transform infrared spectroscopy technique is used for the structural characterization of the hydrogels. Dynamic swelling tests are conducted on acrylamide-based hydrogels for the determination of the swelling characteristics with respect to different crosslinking concentrations at room temperature. The parameters of swelling kinetics and diffusion mechanisms of the hydrogels are calculated with the aid of the data obtained. Accordingly, PEGDMA and EGDMA absorption capacity is found to increase with increasing concentrations. The lowest and highest water absorption capacities in PEGDMA(810) and EGDMA crosslinked hydrogels are 22.73-48.39 and 10.15-16.02 g/g, respectively. Water intake of hydrogels crosslinked by EGDMA and PEGDMAs followed Fickian nature type diffusion except for PEGDM(810), which has a swelling exponent greater than 0.5 and so does not follow a Fickian type of diffusion. PEGDM(810) showed the fastest diffusion rate of between 5.87 x 10(-4) and 10.87 x 10(-4) cm(2) s(-1).