STRUCTURE OF IONIC FLUIDS IN EQUILIBRIUM WITH A MICROPOROUS IONIC MATRIX
PHILOSOPHICAL MAGAZINE LETTERS, cilt.68, ss.357-361, 1993 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 68
- Basım Tarihi: 1993
- Doi Numarası: 10.1080/09500839308242428
- Dergi Adı: PHILOSOPHICAL MAGAZINE LETTERS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.357-361
- Yıldız Teknik Üniversitesi Adresli: Evet
Özet
The Ornstein-Zernike equations for the structure of a fluid of positive ions in equilibrium with a disordered matrix formed by chlorine ions are solved numerically in the hypernetted-chain approximation, and the results are compared with those obtained for the corresponding molten salt at complete equilibrium. Quenching of the halogen framework in a model appropriate to CuCl enhances the delocalization of the Cu ions. A similar, although less striking, reduction in the short-range order of the metal-ion component is accompanied by an enhancement of its state of intermediate-range order in models appropriate to trivalent metal halides with octahedral- or tetrahedral-type coordination.