Synthesis and characterisation of D-pi-D type Schiff base ligands derived from fluorene and 1,10-phenanthroline and its complexes with ruthenium(II)
JOURNAL OF CHEMICAL RESEARCH, sa.2, ss.90-92, 2009 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Basım Tarihi: 2009
- Doi Numarası: 10.3184/030823409x402537
- Dergi Adı: JOURNAL OF CHEMICAL RESEARCH
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.90-92
- Anahtar Kelimeler: Schiff base, D-pi-D, complex, fluorene, 1,10-phenanthroline, TRANSITION-METAL-COMPLEXES, DNA-BINDING, POLYPYRIDYL COMPLEXES, CHEMISTRY, ION
- Yıldız Teknik Üniversitesi Adresli: Evet
Özet
A fluorene derivative, 9H-fluoren-9-one(diphenylmethylene)hydrazone has been synthesised from the reaction of 4,5-diazafluoren-9-one with benzophenone hydrazone and a 1,10-phenanthroline derivative, N-[(1E,2E)-3-phenylprop-2en-1-ylidene]-1,10-phenanthrolin-5-amine has been synthesised from the reaction of 5-amino-1,10-phenanthroline with cinnamaldehyde. Ru(II) complexes of these ligands have been prepared and characterised.