Characterization of jarosites produced by chemical synthesis over a temperature gradient from 2 to 40 degrees C

Bigham J. M. , Jones F. S. , Ozkaya B. , Sahinkaya E., Puhakka J. A. , Tuovinen O. H.

INTERNATIONAL JOURNAL OF MINERAL PROCESSING, vol.94, pp.121-128, 2010 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 94
  • Publication Date: 2010
  • Doi Number: 10.1016/j.minpro.2010.01.005
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.121-128
  • Keywords: Hydronian jarosite, Jarosite synthesis, Potassium jarosite, Solid solution, X-ray diffraction, IRON, SULFATE, SCHWERTMANNITE, SPECIATION, OXIDATION
  • Yıldız Technical University Affiliated: Yes


The purpose of the study was to characterize ferric iron precipitates formed in batch experiments over a temperature range of 2 to 40 degrees C from ferric sulfate and mineral salts in sulfuric acid. With the exception of elevated levels of K+ to promote jarosite [KFe3(SO4)(2)(OH)(6)] formation, the solution composition was intended to simulate fully oxidized bioleaching solutions. Iron-oxidizing acidophilic bacteria were not included in the system. The solutions were held for 10 days in a thermal gradient incubator with a 1.65 degrees C temperature interval followed by analyses of the residual solutions and precipitated solid phases. The loss of dissolved Fe3+ through solid-phase precipitation increased with temperature, consistent with the expected temperature-dependency of the rate of precipitation. Hydronian jarosites [(K,H3O)Fe-3(SO4)(2)(OH)(6)] were the main phases identified in all samples by powder X-ray diffraction (XRD) analysis, but a K and SO4 enriched phase similar to Maus' salt [KSFe3(SO4)(6)(OH)(2)center dot 8H(2)O] was also detected in some samples, mostly those formed at sub-ambient temperatures ( <25 degrees C). Background areas from XRD powder patterns decreased in a linear fashion with increasing temperature of synthesis, suggesting improved crystallinity of the solid phase at the expense of an X-ray amorphous fraction. Spacing differences (Delta 2 theta) between the intense (113) and (021) peaks confirmed the hydronian character of the jarosite phase. The jarosite lattice parameter a(0) decreased whereas c(0) increased with the synthesis temperature, indicating that H3O+ substitution for K+ in the jarosite structure was favored at low temperatures. (C) 2010 Elsevier B.V. All rights reserved.