Synthesis, characterization, electrospinning and antibacterial studies on triphenylphosphine-dithiphosphonates Copper(I) and Silver(I) complexes

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Karakus M., Ikiz Y., Kaya H. I., Simsek Ö.

CHEMISTRY CENTRAL JOURNAL, vol.8, 2014 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 8
  • Publication Date: 2014
  • Doi Number: 10.1186/1752-153x-8-18
  • Journal Name: CHEMISTRY CENTRAL JOURNAL
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Keywords: Dithiophosphonates, Triphenylphosphine, Copper(I) and Silver(I) complexes, Nanofiber, Electrospinning, Antibacterial, MOLECULAR-STRUCTURES, GOLD(I), NANOFIBERS, LIGANDS, FIBERS, DITHIOPHOSPHONATES, NANOPARTICLES, LUMINESCENCE, CRYSTAL, POLYMER
  • Yıldız Technical University Affiliated: No

Abstract

Background: The novel amido and O-ferrocenyldithiophosphonates [FcP(S)(SH)(NHR1)] (Fc = Fe(eta(5)-C5H5)(eta(5)-C5H4), R-1 = 1-(4-fluorophenylethyl and benzyloxycyclopentyl) and [FcP(S)(OR2)S-][H3N+C(CH3)(3)] (R-2 = myrtanyl) were synthesized by the reaction of [(FcPS(2))](2) (Fc = Fe(eta(5)-C5H5)(eta(5)-C5H4)) and chiral amines, such as (S)-(-)-1-(4-fluorophenylethyl) amine and (1S,2S)-(+)-benzyloxycyclopentyl amine, and of (1S), (2S), (5S)-myrtanol in toluene. The reaction of ferrocenyldithiophosphonates and [Cu(PPh3)(2)]NO3 or AgNO3 and PPh3 gave rise to copper(I) and silver(I) complexes in THF. [Ag-2{FcP(OMe)S-2}(2)(PPh3)(2)] and [Cu(PPh3)(2)]NO3 were embedded into nanofibers and their antimicrobial activities on fibers were also investigated.