Synthesis, characterization of new phthalocyanines and investigation of photophysical, photochemical properties and theoretical studies


Tayfuroglu O., Kilicarslan F. A., Atmaca G., Erdoğmuş A.

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, vol.22, pp.250-265, 2018 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 22
  • Publication Date: 2018
  • Doi Number: 10.1142/s1088424618500281
  • Journal Name: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.250-265
  • Keywords: phthalocyanines, fluorescence, aggregation, photochemistry, theoretical chemistry, DFT, SUBSTITUTED ZINC PHTHALOCYANINES, SENSITIZED SOLAR-CELLS, ZN-O COORDINATION, PHOTODYNAMIC THERAPY, MOLECULAR MATERIALS, THIN-FILMS, METAL-FREE, ELECTROCHEMISTRY, METALLOPHTHALOCYANINES, DERIVATIVES
  • Yıldız Technical University Affiliated: Yes

Abstract

This work describes the synthesis, spectral, aggregation and fluorescence properties of bis 4-[(4-tert-butylbenzyl) oxy substituted metal free (2), magnesium (3), zinc (4) and nickel (5) phthalocyanines. The syntheses of the novel compounds were confirmed by FT-IR, UV-vis, mass and NMR spectroscopy techniques, as well as elemental analysis. The effects of the nature of the central metal on the photophysical parameters of the phthalocyanine complexes are reported in this study. The photochemical properties (singlet oxygen quantum yields and photodegradation quantum yields) and photophysical properties (fluorescence behavior and fluorescence quantum yield) of the complexes were reported in different solutions (dimethyl sulfoxide (DMSO) and dimethyl formamide (DMF) and tetrahydrofuran (THF)). However, energy minimized structure, vibrational frequency, molecular orbital levels and electronic absorption spectra were obtained by DFT calculations which supported the experimental results.