Synthesis of N,N '-bis[(benzo-15-crown-5)-oylmethyl]diaminoglyoxime and its metal complexes

AVCIATA, Ulvi; Demirhan, Nebahat; Gul, A

doi:10.1080/00945719909349490

Synthesis of N,N '-bis[(benzo-15-crown-5)-oylmethyl]diaminoglyoxime and its metal complexes

Atıf İçin Kopyala

AVCIATA U., Demirhan N., Gul A.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.29, sa.5, ss.827-840, 1999 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 29 Sayı: 5
Basım Tarihi: 1999
Doi Numarası: 10.1080/00945719909349490
Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.827-840
Yıldız Teknik Üniversitesi Adresli: Evet

Özet

A new macrocyclic ligand (LH2) has been synthesised by the reaction of 4'-omega-aminoacetyl(benzo-15-crown-5) with anti-dichloroglyoxime (EE-diimidoyldichloride-dihydroxyethane). The crystalline complexes of the ligand (LH2) with Cu(II), Ni(II) and Co(II) has also been isolated. Protonation constants of the ligand and overall formation constants have been calculated from potentiometric data using the program TITFIT. Both amino and hydroxyimino groups provide donor atoms together with hydroxyl ions at higher pH values. The order of formation constants of the mononuclear complexes is Cu(II)> U(VI)O-2>Ni(II)> Co(II)> Mn(II).