A study of the thermodynamical interactions with solvents and surface characterisation of liquid crystalline 5-((S)-3,7-dimethyloctyloxy)-2-[[[4-(dodecyloxy)phenyl]imino]-methyl]phenol by inverse gas chromatography

OCAK H., Mutlu-Yanic S., ÇAKAR F., Bilgin-Eran B., GUZELLER D., KARAMAN F., ...Daha Fazla

JOURNAL OF MOLECULAR LIQUIDS, cilt.223, ss.861-867, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 223
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1016/j.molliq.2016.09.002
  • Dergi Adı: JOURNAL OF MOLECULAR LIQUIDS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.861-867
  • Anahtar Kelimeler: Inverse gas chromatography, Liquid crystals, Thermodynamic interaction parameters, Surface properties, MESOMORPHISM
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

An inverse gas chromatography (IGC) study of thermodynamic interactions of a new chiral calamitic liquid crystalline 54(S)-3,7-Dimethyloctyloxy)-2-[[[4-(dodecyloxy)phenyl]imino]methyl]phenol (DODPIMP) with some solvents was presented. The retention diagrams of the solvents on the DODPIMP were plotted by specific retention volumes, V-g(0) at temperatures between 373.2 and 393.2 K. The Flory-Huggins interaction parameter, chi(infinity)(12), the weight fraction activity coefficient, Omega(infinity)(1) and selectivity coefficients, alpha, of the structural isomers were determined for the DODPIMP liquid crystal.