Synthesis, characterization and sensing properties of donor-acceptor systems based Dithieno[3,2-b;2 ',3 '-d]thiophene and boron

Ipek O. S., Topal S., Öztürk T.

DYES AND PIGMENTS, cilt.192, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 192
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1016/j.dyepig.2021.109458
  • Dergi Adı: DYES AND PIGMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, INSPEC, Metadex, Civil Engineering Abstracts
  • Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

Two dithieno[3,2-b;2 ',3 '-d]thiophenes, posessing donor-pi-acceptor (D-pi-A) character through electron donor triphenylamine and electron acceptor boron, were successfully synthesized. They had large Stokes shifts of 140 and 155 nm and exhibited remarkable solvatochromic behaviors. Emission colors changed from blue to orange in non-polar to polar solvents, respectively. They acted as colorimetric and fluorescent chemosensors with high sensitivity towards fuoride anion, displaying a blue shift from yellow upon addition of TBAF as a result of blocking D-A conjugation.