Spectrophotometric determination of iron(II) with 5-nitro-6-amino-1,10-phenanthroline


Demirhan N. , ELMALI F.

TURKISH JOURNAL OF CHEMISTRY, cilt.27, ss.315-321, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 27 Konu: 3
  • Basım Tarihi: 2003
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.315-321

Özet

A new spectrophotometric method is developed for the determination of Fe(II) with 5-nitro-6-amino-1,10-phenanthroline (NAF). In this work, the effect of factors such as pH, amount of reagent (NAF), reaction time and temperature were investigated. The method is based on the formation of a colored product between Fe(II) and NAF. The reaction proceed quantitatively at 20 degreesC for 210 min in acidic medium. The absorption maximum was at 520 nm. A linear relationship existed between absorbance and Fe(II) concentration over the range 0.1 mug/mL and 0.4 mug/mL. The molar ratio of Fe(II) to the reagent was determined as 1:3. The limiting concentration for interference by Co(II), Ni(II), Cu(II), Zn(II), Mn(II), Al(III), Ca(II) and Mg(II) cations are reported.