Using 2-(N-Methyl-N-Phenylamino) acetonaphthone as photoinitiator for the polymerization of methyl methacrylate

Keskin S., Arsu N.

POLYMER BULLETIN, cilt.57, sa.5, ss.643-650, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 57 Sayı: 5
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1007/s00289-006-0620-5
  • Dergi Adı: POLYMER BULLETIN
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.643-650
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

2-(N-Methyl-N-phenylamino) acetonaphthone (MPA) was synthesized as a cleavable photoinitiator and the structure of the photoinitiator was confirmed by spectral and elemental analysis. MPA shows a much higher molar absorptivity than the commercially used acetophenone derivative. The photoinitiation capability of MPA was demonstrated by using methyl methacrylate and a formulation containing multifunctional monomers. Incorporation of the naphthoyl moiety into the polymer was demonstrated by spectroscopic methods.