Unexpected disruption of the dimensionality-driven two-photon absorption enhancement within a multipolar polypyridyl ruthenium complex series

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Durand N., Mhanna R., Savel P., Akdas-Kilic H., Malval J., Soppera O., ...Daha Fazla

Chemical Communications, cilt.56, sa.84, ss.12801-12804, 2020 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 56 Sayı: 84
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1039/d0cc05025c
  • Dergi Adı: Chemical Communications
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Communication Abstracts, EMBASE, MEDLINE, DIALNET
  • Sayfa Sayıları: ss.12801-12804
  • Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

© The Royal Society of Chemistry.The dimensionality-driven two-photon absorption (2PA) enhancement effect is investigated in a series of functionalized bipyridyl Ru-complexes. Our design strategy leads to very high 2PA responses up to ∼1500 GM. However, we highlight that the 2PA performance vs. dimensionality correlation reaches an unexpected limit stemming from 'anti-cooperative' interchromophoric couplings. This journal is