A facile synthesis of various butenolides
SYNTHETIC COMMUNICATIONS, vol.30, no.16, pp.2855-2862, 2000 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 30 Issue: 16
- Publication Date: 2000
- Doi Number: 10.1080/00397910008087436
- Journal Name: SYNTHETIC COMMUNICATIONS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.2855-2862
- Yıldız Technical University Affiliated: Yes
Abstract
The synthesis of alpha'-acyloxy-alpha,beta-unsaturated cyclic ketones from the corresponding alpha,beta-unsaturated cyclic ketones by using manganese (III) acetate in combination with 2-chloropropionic acid followed by subsequent Arbuzov and intramolecular Horner-Emmons cyclization reactions provided a convenient synthetic pathway to various butenolides 4a-d.