Photoinitiated polymerization of beta-cyclodextrin/methyl methacrylate host/guest complex in the presence of water soluble photoinitiator, thioxanthone-catechol-O,O'-diacetic acid
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.68, ss.147-153, 2010 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 68
- Basım Tarihi: 2010
- Doi Numarası: 10.1007/s10847-010-9760-1
- Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.147-153
- Yıldız Teknik Üniversitesi Adresli: Evet
Özet
beta-Cyclodextrin (beta-CD) was used to complex the monomer, methyl methacrylate (MMA), yielding a water-soluble host/guest complex. Photoinitiated polymerization of beta-CD/MMA complex was achieved in the presence of thioxanthone-catechol-O,O'-diacetic acid (TX-Ct), a one component water soluble photoinitiator. Photodecarboxylation of TX-Ct in water seems to be an important reaction mechanism. Therefore, resulting alkyl radicals are able to initiate the polymerization of beta-CD/MMA host/guest complex in water.