The influence of polyelectrolytes architecture on calcium sulfate dihydrate growth retardation


ONER M. , Dogan O. , ONER G.

JOURNAL OF CRYSTAL GROWTH, vol.186, no.3, pp.427-437, 1998 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 186 Issue: 3
  • Publication Date: 1998
  • Doi Number: 10.1016/s0022-0248(97)00518-6
  • Title of Journal : JOURNAL OF CRYSTAL GROWTH
  • Page Numbers: pp.427-437

Abstract

The retarding influence of acidic acrylate and methacrylate polymers made by group transfer polymerization on the growth of calcium sulfate dihydrate was examined in aqueous solution. The variations with polyelectrolyte charge, structure and molecular weight have been tested. The inhibition increases with the acid content of the polymers. Acrylates were much more effective than equivalent methacrylates. The higher inhibition efficiency is related to the maximum surface charge density due to adsorbed polymer. (C) 1998 Elsevier Science B.V. All rights reserved.