Polymerization of maleic anhydride-modified plant oils with polyols


Eren T. , KUSEFOGLU S., WOOL R.

JOURNAL OF APPLIED POLYMER SCIENCE, cilt.90, ss.197-202, 2003 (SCI İndekslerine Giren Dergi)

  • Cilt numarası: 90 Konu: 1
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1002/app.12631
  • Dergi Adı: JOURNAL OF APPLIED POLYMER SCIENCE
  • Sayfa Sayısı: ss.197-202

Özet

In this study soybean oil triglycerides were reacted with maleic anhydride in an ene reaction to introduce more than two maleate residues per triglycerides. The maleinized soybean oil (SOMA) was then polymerized with diols to the half-ester stage only. Two different types of alcohols was used in this work: (1) short-chain polyhydroxy linear or cyclic alcohols having 2, 3, 4, or 6 hydroxyl groups; and (2) long-chain dihydroxy alcohols. The aim was to determine the effect of functionality and chain length by choosing alcohols with increasing number of hydroxyl groups and different chain lengths. The reaction of alcohols with anhydride functionalized soybean oil to give a polymeric half-ester is a reaction that proceeds without the formation of byproducts and is different from complete polyesterification of maleinized oils, which are well known. To improve the reaction yields, different catalysts and different reaction conditions were examined. The structural analysis of the products was done with H-1-NMR and IR spectroscopy. All of the new polymers obtained were resilient and soft rubbers at room temperature. Castor oil polymer mixed with 60% CaCO3 and 12% cork powder gave a resilient and nontacky linoleum composition. (C) 2003 Wiley Periodicals, Inc.