Photoinitiated crosslinking and grafting of methylmethacrylate using N,N-dimethyl amino functional polystyrene block copolymers


Muftuoglu A. E. , YAGCI Y., SE K.

TURKISH JOURNAL OF CHEMISTRY, cilt.28, ss.469-476, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 28 Konu: 4
  • Basım Tarihi: 2004
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.469-476

Özet

Monodisperse poly(N, N-dimethyl-4-vinylphenethylamine)-block-polystyrene was synthesized via anionic living polymerization carried out at -78 degreesC under a pressure of 10(-6) torr using cumyl potassium as the initiator. Subsequent photoinduced radical polymerization of styrene through side chain-functional N,N-dimethyl amino groups yielded a crosslinked polymer and a brush type block-graft copolymer to a lesser extent. Upon irradiation at a wavelength of 350 nm, macroradicals were generated via hydrogen abstraction from amino side-chain groups by the excited benzophenone. The block-graft copolymer was characterized by H-1-NMR, IR, and GPC analysis.