Host/guest complex of beta-cyclodextrin/5-thia pentacene-14-one for photoinitiated polymerization of acrylamide in water

BALTA, Demet; ARSU, Nergis

doi:10.1016/j.jphotochem.2008.08.017

Host/guest complex of beta-cyclodextrin/5-thia pentacene-14-one for photoinitiated polymerization of acrylamide in water

Atıf İçin Kopyala

BALTA D., ARSU N.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, cilt.200, ss.377-380, 2008 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 200
Basım Tarihi: 2008
Doi Numarası: 10.1016/j.jphotochem.2008.08.017
Dergi Adı: JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.377-380
Yıldız Teknik Üniversitesi Adresli: Evet

Özet

beta-Cyclodextrin (beta-CD) was used to complex the photoinitiator, 5-thia pentacene-14-one (TX-A), yielding a water-soluble host/guest complex. IR, UV-Vis and fluorescence spectroscopy were employed to characterize complexed beta-CD/TX-A. Photoinitiated polymerization of acrylamide in water was achieved with beta-CD/TX-A in the presence of N-methyldiethanolamine (MDEA). Excellent polymerization yields were observed in air saturated solutions when MDEA was added. (C) 2008 Elsevier B.V. All rights reserved.