Development of a magnetic nanocomposite sorbent (NiCoMn/Fe3O4@C) for efficient extraction of methylene blue and Auramine O

Gholami Z., YETİLMEZSOY K., Ahmadi Azqhandi M. H.

Chemosphere, vol.355, 2024 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: 355
  • Publication Date: 2024
  • Doi Number: 10.1016/j.chemosphere.2024.141792
  • Journal Name: Chemosphere
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Artic & Antarctic Regions, BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, Environment Index, Food Science & Technology Abstracts, Geobase, Greenfile, Metadex, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Civil Engineering Abstracts
  • Keywords: Extraction, GA, GRNN, Preconcentration, Recovery
  • Yıldız Technical University Affiliated: Yes

Abstract

A rapid and efficient method for the simultaneous monitoring and recovery of Auramine O (AO) and Methylene Blue (MB) dyes from water samples is presented. This method, named ultrasound-assisted dispersive-magnetic nanocomposites-solid-phase microextraction (UA-DMN-μSPE), utilizes NiCoMn/Fe3O4@C composite sorbents. Response surface methodology (RSM) combined with artificial neural networks (ANN) and generalized regression artificial neural network (GRNN) under central composite design (CCD) was employed to optimize various parameters for efficient extraction, followed by further refinement using desirability function analysis (DFA) and genetic algorithms (GA). Under optimized conditions, the method achieved exceptional recovery rates (99.5 ± 1.2% for AO and 99.8 ± 1.1% for MB) with acetone as the eluent. Additionally, a high preconcentration factor of 45.50 and 47.30 for AO and MB, respectively, was obtained. Low detection limits of 0.45 ng mL⁻1 (AO) and 1.80 ng mL⁻1 (MB) were achieved with wide linear response ranges (5–1000 and 5–2000 ng mL⁻1 for AO and MB, respectively). The method exhibited good stability with RSDs below 3% for five recycling runs, and minimal interference from various ions was observed. This UA-DMN-μSPE-UV/Vis method offers significant advantages in terms of efficiency, preconcentration, and detection limits, making it a valuable tool for the analysis of AO and MB in water samples.